VANADYL ISOPROPOXIDE

PRODUCT IDENTIFICATION

CAS RN

5588-84-1

EINECS RN

226-997-4

FORMULA

OV(OCH(CH₃)₂)₃

MOLE WEIGHT

244.20

H.S CODE

SMILES

CLASSIFICATION

EXTRA NOTES

Other RN: 863098-64-0
Flammable liquid, corrosive

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE.

clear liquid

MELTING POINT

BOILING POINT

82 C at 2 mmHg (Decomposes)

DENSITY

1.035

SOLUBILITY IN WATER

Reacts exothermally

Soluble in hydrocarbons, reacts with alcohols, ketones and esters

VAPOR DENSITY

log P(octanol-water)

VAPOR PRESSURE

AUTOIGNITION TEMP

REFRACTIVE INDEX

1.479

FLASH POINT

45 C

INCOMPATIBLE MATERIALS

Strong oxidizing agents, Strong acids, Strong bases

Has not been reported

NFPA RATINGS

Health: 2, Flammability: 2, Reactivity: 0

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Vanadium(V) oxytriisopropoxide

Google Scholar Search - Vanadium(V) oxytriisopropoxide

PubChem Compound Summary - Vanadium(V) oxytriisopropoxide

NCBI (http://www.ncbi.nlm.nih.gov/) -  Vanadium(V) oxytriisopropoxide

Material Safety Data Sheet - Vanadium(V) oxytriisopropoxide

www.sigmaaldrich.com/
Application: Building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis

SALES SPECIFICATION

APPEARANCE

clear liquid

ASSAY

98% min

INSOLUBLES (IN HEXANE)

100 ppm max

TRACE ELEMENTS

Al <20 ppm
Ca <10 ppm
Fe <30 ppm
K <10 ppm
Na <10 ppm
Sn <10 ppm
Ti <50 ppm
Zn <30 ppm

TRANSPORT & REGULATORY INFORMATION

UN NO.

1993

HAZARD CLASS

3

HAZARD OVERVIEW

GHS (Globally Harmonised System) Classification: Flammable liquids, Skin irritation, Eye irritation, Specific target organ toxicity - single exposure, Respiratory system,. Hazard statements: Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

PICTOGRAMS

HAZARD STATEMENTS

H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

PRECAUTIONARY STATEMENTS

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P321 Specific treatment (see supplemental first aid instructions on this label).
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.

RISK PHRASES

10 Flammable
36/37/38 Irritating to eyes, respiratory system and skin

SAFETY PHRASES

16 Keep away from sources of ignition - No smoking
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36 Wear suitable protective clothing.

PACKING

Preserve in light-resistant and well-closed containers

PRICE INFORMATION